... Sayre51Department of Biochemistry,2Laboratory of Growth Regulators, and 3Department of Analytical Chemistry, Faculty of Science,Palacky´University, Olomouc, Czech Republic;4Department of Analytical ... (fragmentation: m/z 317.3, 305.2, 291.1, 253.2 and 240.1), 350.2 (fragmentation: m/z 333.2 and 307.1) and 431.3 (fragmentation: m/z 414.3, 388.3 and 337.1).MALDI-TOF-MS of the separated peak 1 provided asingle ... additionally demonstra-ted the presence of a triple bond (d 74.3 and 82.7 p.p.m) and aliphatic carbon atoms (signals of d 20–40 p.p.m), consis-tent with presence of an unoxidized DAPY moiety.The...